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Patent Granted A metallic glass laminate of the present invention is characterized in that a thermal sprayed coating layer of a metallic glass of amorphous phase is formed on the substrate surface, and there is no continuous pore (pinhole) through the thermal sprayed coating layer of the metallic glass , wherein the supercooled liquid temperature range Tx of the metallic glass is equal to or more than 30 DEG C, and wherein the porosity of the thermal sprayed coating layer of the metallic glass is equal to or less than 2%.