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Patent Granted Polymerization of alkenes is a reaction that yields polymers of high industrial value at great economy, such as the plastics polyethylene and polypropylene. Polymers from alkene monomers are referred to in a general way as polyolefins or in rare instances as polyalkenes. A polymer from alpha-olefins is called a polyalphaolefin (PAO). Polymerization can proceed via either a free-radical or an ionic mechanism, converting the double to a single bond and forming single bonds to join the other monomers.