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Patent Pending A hybrid nanocomposite useful as a cathode in high discharge capacity rechargeable batteries is provided. The nanocomposite includes polyaniline macromolecules in the state of emeraldine base that are located between 2D particles of nanostructured graphite or few-layered graphene. The nanocomposite possesses high charge/discharge characteristics. A solvent-free mechanochemical method for the preparation of the hybrid nanocomposites is also provided.