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特許 権利維持 In-situ leaching of copper was done by the Chinese by 977 AD, and perhaps as early as 177 BC.[2] Copper is usually leached using acid (sulfuric acid or hydrochloric acid), then recovered from solution by solvent extraction electrowinning (SX-EW) or by chemical precipitation. Ores most amenable to leaching include the copper carbonates malachite and azurite, the oxide tenorite, and the silicate chrysocolla. Other copper minerals, such as the oxide cuprite and the sulfide chalcocite may require addition of oxidizing agents such as ferric sulfate and oxygen to the leachate before the minerals are dissolved.